來源:本站原創2015年12月14日
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浙江大學
聚碳酸酯多元醇,高性能/無鹵阻燃環氧樹脂,3D打印線材和光固,油墨技術及產品
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13588846711
xhzhang@zju.edu.cn
張興宏
77975232
男
d_xhzhang
浙江大學高分子科學與工程學系副教授,博士,博士生導師。近年來作為項目負責人主持國家自然科學基金項目4項;浙江省杰出青年基金項目1項;中國博士后自然科學基金一等資助項目1項;浙江省自然科學基金項目1項;浙江省科技廳社會公益技術項目1項;承擔香港建滔化工集團、德國巴斯夫委托的國內外研究課題4項。在Chemical Science, Macromolecules, Polymer Chemistry, Macromolecular Rapid Communications, Journal of polymer science Part A: Polymer Chemistry, Polymer 等國內外期刊發表 SCI論文50余篇,授權中國發明專利20項,授權美國專利1項。
主持/參與科研項目
主持的國家級項目:
1、一釜合成多嵌段CO2基共聚物及其結構與性能、國家自然科學基金面上項目、2015/01-2018/12。
2、氧硫化碳-環氧化物可控催化共聚及機理研究、國家自然科學基金面上項目、2013/01-2016/12。
3、基于CO2/環氧化物可控共聚技術合成可降解的聚合物分子刷、國家自然科學基金面上項目、2011/01-2013/12。
專利、論文及著作
代表性專利:
1. Metal cyanide complex catalyst, preparation method and uses thereof,美國發明專利,授權,US13394267,2014.10, 1/5。
2. 一種鏈結構規整的聚單硫代碳酸酯的制備方法 ,發明專利,授權,201310202810.0, 2015.05,1/4。
3. 一種用于碳酸二甲酯合成的催化劑的制備方法及應用,發明專利,授權,201210148342.9,2014.04,1/4。
4. 一種納米結構環氧樹脂固化物的制備方法和用途,發明專利,授權,201010225029.1,2012.03,1/3。
5. 一種鏈結構規整的脂肪族聚碳酸酯的合成方法,發明專利,授權, 201310035031.6,2015.02,1/3。
6. 一種雙組分雙金屬催化劑的合成方法及應用,發明專利,授權, 201110428195.6,2015.04,1/4。
7. 含聚酯鏈節和聚碳酸酯鏈節的三元共聚物及其合成方法,發明專利,授權,200910098650.3,2011.05,1/3。
8. 主鏈和側鏈均為碳-氧雜鏈結構的聚合物分子刷、合成方法,發明專利,授權, 201110249714.2,2013.08,1/5。
9. 金屬氰化物配位催化劑催化制備脂肪族聚碳酸酯的方法,發明專利,授權, 201010253928.2,2012.05,1/5。
10. 一種金屬氰化物配位催化劑及其制備方法和應用,發明專利,授權,201010253936.7,2012.05,1/5。
論文:
2015
(1) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Well-defined high refractive index poly(monothiocarbonate) with tunable Abbe's numbers and glass-transition temperatures via terpolymerization. Polymer Chemistry 2015, 6, 4978-4983.
(2) Li, Y.; Hong, J.-L.; Wei, R.-J.; Zhang, Y.-Y.; Tong, Z.-Z.; Zhang, X.-H.*; Du, B.-Y.; Xu, J.-T.; Fan, Z.-Q. Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone. Chemical Science 2015, 6, 1530-1536.
(3) Zhang, Y.-Y.; Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Efficient solvent-free alternating copolymerization of CO2 with 1, 2-epoxydodecane and terpolymerization with styrene oxide via heterogeneous catalysis. Journal of Polymer Science Part A: Polymer Chemistry 2015, 53, 737-744.
(4) Zhang, Y.-Y.; Li, Y.; Zhou, X.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Synthesis of an Amphiphilic Brush Copolymer by a Highly Efficient “Grafting onto” Approach via CO2 Chemistry. Macromolecular Rapid Communications 2015, 36, 852-857.
(5) Zhang, X.-H.*; Wei, R.-J.; Zhang, Y.-Y.; Du, B.-Y.; Fan, Z.-Q. Carbon Dioxide/Epoxide Copolymerization via a Nanosized Zinc–Cobalt(III) Double Metal Cyanide Complex: Substituent Effects of Epoxides on Polycarbonate Selectivity, Regioselectivity and Glass Transition Temperatures. Macromolecules 2015, 48, 536-544.
(6) Min, Y.-Q.; Huang, S.-Y.; Wang, Y.-X.; Zhang, Z.-J.; Du, B.-Y.; Zhang, X.-H.*; Fan, Z.-Q. Sonochemical Transformation of Epoxy–Amine Thermoset into Soluble and Reusable Polymers. Macromolecules 2015, 48, 316-322.
(7) Luo, M.; Zhang, X.-H.*; Darensbourg, D. J. An Investigation of the Pathways for Oxygen/Sulfur Scramblings during the Copolymerization of Carbon Disulfide and Oxetane. Macromolecules 2015, 48, 5526-5532.
(8) Luo, M.; Zhang, X.-H.*; Darensbourg, D. J. An Examination of the Steric and Electronic Effects in the Copolymerization of Carbonyl Sulfide and Styrene Oxide. Macromolecules 2015, 48, 6057-6062.
(9) Luo, M.; Zhang, X. H.*; Darensbourg, D. J. Highly regioselective and alternating copolymerization of carbonyl sulfide with phenyl glycidyl ether. Polymer Chemistry 2015, 6, 6955-6958.
(10)Luo, M.; Zhang, X. H.*; Darensbourg, D. J. Synthesis of cyclic monothiocarbonates via the coupling reaction of carbonyl sulfide (COS) with epoxides. Catalysis Science & Technology 2015. Advance Article. DOI: 10.1039/C5CY00977D
2014
(1) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Alternating copolymerization of carbonyl sulfide and Cyclohexene Oxide catalyzed by zinc–cobalt double metal cyanide complex. Polymer 2014, 55, 3688-3695.
(2) Wei, R.-J.; Zhang, X.-H.*; Zhang, Y.-Y.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Functional poly (carbonate-co-ether) synthesis from glycidyl methacrylate/CO2 copolymerization catalyzed by Zn–Co (III) double metal cyanide complex catalyst. RSC Advances 2014, 4, 3188-3194.
(3) Wei, R.-J.; Zhang, Y.-Y.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Regio-selective synthesis of polyepichlorohydrin diol using Zn–Co (III) double metal cyanide complex. RSC Advances 2014, 4, 21765-21771.
(4) Zhang, Y.-Y.; Zhang, X.-H.*; Wei, R.-J.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Synthesis of fully alternating polycarbonate with low T g from carbon dioxide and bio-based fatty acid. RSC Advances 2014, 4, 36183-36188.
(5) Zhang, X.-H.*; Min, Y.-Q.; Hua, Z.-J. Epoxy-Based Electronic Materials Containing Nitrogen Heterocyclic Ring: Flame Retardancy. Progress in chemistry 2014, 26, 1021-1031.
(6) Hong, J.-L.; Zhang, X.-H.*; Wei, R.-J.; Wang, Q.; Fan, Z.- Q.; Qi, G.-R. Inhibitory effect of hydrogen bonding on thermal decomposition of the nanocrystalline cellulose/poly (propylene carbonate) nanocomposite. Journal of Applied Polymer Science 2014, 131.
(7) Zhou, X.-J.; Zhou, Y.-Y.; Nie, J.-J.; Xu, J.-T.; Zhang, X.-H.; Du, B.-Y.* Thermosensitive Ionic Microgels
via Surfactant-Free Emulsion Copolymerization and in Situ Quaternization Cross-Linking. ACS Applied Materials & Interfaces 2014, 6, 4498-4513.
(8) Chen, T.-Q.; Lu, Y.-P.; Chen, T.-Y.; Zhang, X.-H.; Du, B.-Y.* Adsorption of PNIPAm x-PEO 20-PPO 70-PEO 20-PNIPAm x pentablock terpolymer on gold surfaces: effects of concentration, temperature, block length, and surface properties. Physical Chemistry Chemical Physics 2014, 16, 5536-5544.
2013
(1) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Sun, X.-K.; Fan, Z.-Q.; Qi, G.-R. Highly Regioselective and Alternating Copolymerization of Racemic Styrene Oxide and Carbon Dioxide via Heterogeneous Double Metal Cyanide Complex Catalyst. Macromolecules 2013, 46, 3693-3697.
(2) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Regioselective and Alternating Copolymerization of Carbonyl Sulfide with Racemic Propylene Oxide. Macromolecules 2013, 46, 5899-5904.
(3) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Selective production of poly (carbonate–co–ether) over cyclic carbonate for epichlorohydrin and CO2 copolymerization via heterogeneous catalysis of Zn–Co (III) double metal cyanide complex. Polymer 2013, 54, 6357-6362.
(4) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Synthesis of bis (cyclic carbonate) and propylene carbonate via a one-pot coupling reaction of CO2, bisepoxide and propylene oxide. RSC Advances 2013, 3, 17307-17313.
(5) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Highly Active and Selective Binary Catalyst System for the Coupling Reaction of CO2 and Hydrous Epoxides. Journal of Molecular Catalysis A: Chemical 2013, 379, 38-45.
(6) Lu, Y.-P.; Chen, T.-Q.; Mei, A.-X.; Chen, T.-Y.; Ding, Y.-W.; Zhang, X.-H.; Xu, J.-T.; Fan, Z.-Q.; Du, B.-Y.* Solution behaviors and microstructures of PNIPAm-P123-PNIPAm pentablock terpolymers in dilute and concentrated aqueous solutions. Physical Chemistry Chemical Physics 2013, 15, 8276-8286.
(7) Chen, T.-Y.; Du, B.-Y.*; Zhang, X.-H.; Fan, Z.-Q. Fabrication of Polymer Nanocapsules with Controllable Oligo (Ethylene Glycol) Densities, Permeation Properties and Robustly Crosslinked Walls. ACS Applied Materials & Interfaces 2013, 5, 3748-3756.
2012
(1) Sun, X.-K.; Zhang, X.-H.*; Wei, R.-J.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. Mechanistic insight into initiation and chain transfer reaction of CO2/cyclohexene oxide copolymerization catalyzed by zinc-cobalt double metal cyanide complex catalysts. Journal of Polymer Science Part A: Polymer Chemistry 2012, 50, 2924-2934.
(2) Sun, X.-K.; Chen, S.; Zhang, X.-H.*; Qi, G.-R. Double Metal Cyanide Complex Catalyst and Its Catalysis for Epoxides-Involved Polymerization. Progress in Chemistry 2012, 24, 1776-1784.
(3) Lu, Y.-P.; Zhang, X.-H.; Fan, Z.-Q.; Du, B.-Y.* Adsorption of PNIPAm 110-PEO 100-PPO 65-PEO 100-PNIPAm 110 pentablock terpolymer on hydrophobic gold. Polymer 2012, 53, 3791-3801.
2011
(1) Zhang, J.-F.; Ren, W.-M.; Sun, X.-K.; Meng, Y.; Du, B.-Y.; Zhang, X.-H.* Fully Degradable and Well-Defined Brush Copolymers from Combination of Living CO2/Epoxide Copolymerization, Thiol–Ene Click Reaction and ROP of ε-caprolactone. Macromolecules 2011, 44, 9882-9886.
(2) Zhang, X.-H.*; Wei, R.-J.; Sun, X.-K.; Zhang, J.-F.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Selective copolymerization of carbon dioxide with propylene oxide catalyzed by a nanolamellar double metal cyanide complex catalyst at low polymerization temperatures. Polymer 2011, 52, 5494-5502.
(3) Meng, Y.; Zhang, X.-H.*; Du, B.-Y.; Zhou, B.-X.; Zhou, X.; Qi, G.-R. Thermosets with core–shell nanodomain by incorporation of core crosslinked star polymer into epoxy resin. Polymer 2011, 52, 391-399.
2010
(1) Sun, X.-K.; Zhang, X.-H.*; Chen, S.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. One-pot terpolymerization of CO2, cyclohexene oxide and maleic anhydride using a highly active heterogeneous double metal cyanide complex catalyst. Polymer 2010, 51, 5719-5725.
(2) Mei, A.-X.; Guo, X.-L.; Ding, Y.; Zhang, X.-H.; Xu, J.-T.; Fan, Z.-Q.; Du, B.-Y.* PNIPAm-PEO-PPO-PEO-PNIPAm pentablock terpolymer: synthesis and chain behavior in aqueous solution. Macromolecules 2010, 43, 7312-7320.
(3) Huang, Y.-J.; Zhang, X.-H.*; Hua, Z.-J.; Qi, G.-R. Calcium chloride doped zinc-cobalt metal-cyanide complex: Unexpected highly activity towards ring-opening polymerization of propylene oxide. Chinese Chemical Letters 2010, 21, 897-901.
(4) Huang, Y.-J.; Zhang, X.-H.*; Hua, Z.-J.; Chen, S.-L.; Qi, G.-R. Ring‐Opening Polymerization of Propylene Oxide Catalyzed by a Calcium‐Chloride‐Modified Zinc‐Cobalt Double Metal‐Cyanide Complex. Macromolecular Chemistry and Physics 2010, 211, 1229-1237.
2009
(1) Zhou, B.-X.; Huang, Y.-J.; Zhang, X.-H.*; Fu, Z.-S.; Qi, G.-R. Thermal properties of an epoxy cresol‐formaldehyde novolac/diaminodiphenyl sulfone system modified by bismaleimide containing tetramethylbiphenyl and aromatic ether structures. Polymer Engineering & Science 2009, 49, 1525-1532.
(2) Zhang, X.-H.*; Zhou, B.-X.; Sun, X.-K.; Qi, G.-R. Cure kinetics and thermal properties of tetramethylbiphenyl epoxy resin/phthalazinone‐containing diamine/hexa (phenoxy) cyclotriphophazene system. Journal of Applied Polymer Science 2009, 114, 1397-1404.
(3) Huang, Z.-Z.; Zhang, X.-H.*; Qi, G.-R. Novel halogen-free flame retardant thermoset from a hybrid hexakis (methoxymethyl) melamine/phosphorus-containing epoxy resin cured with phenol formaldehyde novolac. Express Polym. Lett 2009, 3, 788-796.
(4) Du, B.-Y.*; Cao, Z.; Li, Z.-B.; Mei, A.-X.; Zhang, X.-H.*; Nie, J.-J.; Xu, J.-T.; Fan, Z.-Q. One-Pot preparation of hollow silica spheres by using thermosensitive poly (N-isopropylacrylamide) as a reversible template. Langmuir 2009, 25, 12367-12373.
2008
(1) Zhang, X.-H.*; Liu, F.; Sun, X.-K.; Chen, S.; Du, B.-Y.; Qi, G.-R.; Wan, K.-M. Atom-exchange coordination polymerization of carbon disulfide and propylene oxide by a highly effective double-metal cyanide complex. Macromolecules 2008, 41, 1587-1590.
(2) Zhang, X.-H.*; Zhou, B.-X.; Sun, X.-K.; Qi, G.-R. Preparation and properties of epoxy/phenol formaldehyde novolac/hexakis (methoxymethyl) melamine hybrid resins from in situ polymerization. Journal of Applied Polymer Science 2008, 110, 4084-4092.
(3) Sun, X.-K.; Zhang, X.-H.*; Liu, F.; Chen, S.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. Alternating copolymerization of carbon dioxide and cyclohexene oxide catalyzed by silicon dioxide/Zn-Co(III) double metal cyanide complex hybrid catalysts with a nanolamellar structure. Journal of Polymer Science Part A:Polymer Chemistry 2008, 46, 3128-3139.
2007
(1) Zhang, X.-H.; Hua, Z.-J.; Chen, S.; Liu, F.; Sun, X.-K.; Qi, G.-R.* Role of zinc chloride and complexing agents in highly active double metal cyanide catalysts for ring-opening polymerization of propylene oxide. Applied Catalysis A: General 2007, 325, 91-98.
(2) Zhang, X.-H.; Liu, F.; Chen, S.; Qi, G.-R.* Novel flame retardant thermosets from nitrogen‐containing and phosphorus‐containing epoxy resins cured with dicyandiamide. Journal of Applied Polymer Science 2007, 106, 2391-2397.
(3) Zhang, X.-H.; Chen, S.; Wu, X.-M.; Sun, X.-K.; Liu, F.; Qi, G.-R.* Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2. Chinese Chemical Letters 2007, 18, 887-890.
(4) Zhang, X.-H.*; Huang, L.-H.; Chen, S.; Qi, G.-R. Improvement of thermal properties and flame retardancy of epoxy-amine thermosets by introducing bisphenol containing azomethine moiety. eXPRESS Polymer Letters 2007, 1, 326-332.
(5) Zhang, X.-H.; Chen, S.; Chen, T.; Sun, X.-K.; Liu, F.; Qi, G.-R.* Synthesis of a soluble azomethine‐containing bisphenol and the properties of its modified epoxy thermosets. Journal of Applied Polymer Science 2007, 106, 1632-1639.
(6) Chen, S.; Zhang, X.-H.; Lin, F.; Qi, G.-R.* Preparation of double metal cyanide compleces from water-insoluble zinc compounds and their catalytic performance for copolymerization of epoxide and CO2. Reaction Kinetics and Catalysis Letters 2007, 91, 69-75.
2006
(1) Zhang, X.-H.; Chen, S.; Min, Y.-Q.; Qi, G.-R.* Synthesis of novel bisphenol containing phthalazinone and azomethine moieties and thermal properties of cured diamine/bisphenol/DGEBA polymers. Polymer 2006, 47, 1785-1795.
(2) Zhang, X.-H.; Min, Y.-Q.; Zhao, H.; Wan, H.-M.; Qi, G.-R.* Novel nitrogen‐containing epoxy resin. II. Cure kinetics by differential scanning calorimetry. Journal of Applied Polymer Science 2006, 100, 3483-3489.
著作:
1, Yuan Meng, Xinghong Zhang*. Nanostructure Formation in Thermoset/Block Copolymer and Thermoset/Hyperbranched Polymer Blends (pages 161-194, Chapter 6 of book: Nanostructured Polymer Blends, edited by Sabu Thomas, Robert Shanks et al), Elsevier Inc, 2013-12, ISBN(ASIN): 1455731595, 條形碼: 978-1-4557-3159-6, William Andrew publishing(出版社);叢書名: Micro & Nano Technologies
2, Yuan Meng, Xinghong Zhang*. Nanostructured epoxy composites (Chapter 3 of book: Micro and Nanostructured Epoxy/Rubber Blends), Wiley-VCH Verlag GmbH, 2014-02. ISBN(ASIN) 3527333347,條形碼:978-3-527-33334-9, Germany.
提供技術
聚碳酸酯多元醇合成技術及其產品;
高性能/無鹵阻燃環氧樹脂;
綠色增塑劑;
3D打印線材和光固化油墨技術及產品。
獲得榮譽
1、發表在Polymer上的論文《Selective copolymerization of carbon dioxide with propylene oxide catalyzed by a nanolamellar double metal cyanide complex catalyst at low polymerization temperatures》 (2011, 52(24), 5494-5502)獲得2012年度馮新德最佳論文提名獎(ELSEVIER出版社)。
2、 2014年 《粘接》雜志,《非異氰酸酯路線合成聚羥氨酯的研究》在“中國膠粘劑行業首屆優秀科技論文有獎征文大賽”中,獲得“杰出獎”論文的榮譽。
3、
2013年浙江大學求是青年學者;
2012年浙江省自然科學學術獎三等獎,排名1;
2012年校級教學成果獎,排名第五;
浙江大學2014年度院級先進工作者.
團體/社會/學術兼職
1. 國家自然科學基金評審專家;浙江省自然科學基金通訊評議人
2. 浙江省粘接技術協會常務理事(2014-2019);
3.《粘接》雜志特約撰稿人(2015-2017)。
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